最近の論文から

T. Kaneko, T. Takao, “Reaction of a Triruthenium μ3-Borylene Complex with Benzonitrile: Formation of a μ3-η3-BCN Ring on a Cationic Ru3 Plane via Photo-Induced Intramolecular Borylene Transfer”, Organometallics, 39, 4, 593-604 (2020). 10.1021/acs.organomet.9b00831

T. Takao, T. Kawashima, R. Nagae, H. Kanda, W. Watanabe, “Diruthenium complexes having a partially hydrogenated bipyridine ligand: plausible mechanism for the dehydrogenative coupling of pyridines at a diruthenium site”, Faraday Discuss. 220, 249-268 (2019). 10.1039/c9fd00029a

R. Shimogawa, Y. Tsurumaki, H. Suzuki, T. Takao, “Selective Synthesis of a Triruthenium Pentahydrido Complex with Mixed-Cp Ligands (C5tBu3H2 and C5Me5) and Its Transformation into Face-Capping Benzene Complexes: Fluxionality of a Face-Capping Benzene Ligand Induced by Oxidation”, Organometallics, 38, 19, 3824-3833 (2019). 10.1021/acs.organomet.9b00503

H. Chikamori, T. Takao, “Formation of a μ3-Acetylide on a Ru3 Cluster via Coupling of μ-Methylene with Isocyanide Accompanied by Elimination of Amine: A Model of Hydrogen-Assisted C–C Bond Formation on a Metal Surface”, Organometallics, 38, 14, 2705–2709 (2019). 10.1021/acs.organomet.9b00301

T. Kaneko, H. Ninagawa, M. Matsuoka, T. Takao, “Synthesis and Properties of a Triruthenium Hydrido Complex Capped by a μ3-Oxoboryl Ligand”, Organometallics, 38, 2239-2249 (2019). 10.1021/acs.organomet.9b00182

M. Saito, S. Kojima, A. Inagaki, K. Seki, T. Takao, “Effect of ring size on the properties of μ3-Cycloalkyne complexes: Synthesis of triruthenium complexes containing a perpendicularly coordinated μ3-Allenyl ligand”, J. Organomet. Chem, 885, 7-20 (2019). 10.1016/j.jorganchem.2019.01.020

H. Chikamori, A. Tahara, T. Takao, “Transformation of a μ3-Benzyne Ligand into Phenol on a Cationic Triruthenium Cluster Supported by a μ3-Sulfido Ligand”, Organometallics, 38, 527-535 (2019). 10.1021/acs.organomet.8b00832

T. Kosukegawa, T. Takao, “Synthesis of a heterometallic spiked tetrahedral cluster of ruthenium and nickel containing multiple hydrido ligands and its degradation to a tetrahedral NiRu3 cluster”, J. Organomet. Chem, 882, 70-79 (2019). 10.1016/j.jorganchem.2018.12.016

T. Takao, S. Horikoshi, T. Kawashima, S. Asano, Y. Takahashi, A. Sawano, H. Suzuki, “Catalytic Hydrogenation of Benzonitrile by Triruthenium Clusters: Consecutive Transformations of Benzonitrile on the Face of a Ru3 Plane”, Organometallics, 37, 1598-1614 (2018). 10.1021/acs.organomet.8b00165

R. Shimogawa, Y. Tusumaki, T. Kuzutani, T. Takao, “σ‑Coordination of a P−H Bond at a Sterically Demanding Diruthenium Site: Tautomerization between Agostic μ‑Phosphane and μ‑Phosphanido Complexes via an η2‑P−H Bond Cleavage”, Organometallics, 37, 290–293 (2018). 10.1021/acs.organomet.7b00856

H. Tsuruda, Y. Hayashi, S. Kawauchi, T. Takao, “Preparation of Bis(μ3-silylyne) Complexes via Consecutive Si–H Bond Cleavage at a Triruthenium Site”, Organometallics, 36, 3774–3783 (2017). 10.1021/acs.organomet.7b00548

Y. Takahashi, Y. Nakajima, H. Suzuki, T. Takao, “Synthesis of an Electron-Deficient Triruthenium Hydrido Complex Having a Bridging Carbonyl Ligand: Influence of a CO Ligand on the Properties and Reactivities of a Hydrido Cluster”, Organometallics, 36, 3539–3552 (2017). 10.1021/acs.organomet.7b00465

R. Shimogawa, R. Fujita, T. Takao, H. Suzuki, “Dehydrogenative Oxidation of Cyclic Amines on a Diruthenium Complex”, Organometallics, 36, 1893-1896 (2017). 10.1021/acs.organomet.7b00231

H. Kameo, Y. Ito, R. Shimogawa, A. Koizumi, H. Chikamori, J. Fujimoto, H. Suzuki, T. Takao, “Synthesis and characterisation of tetranuclear ruthenium polyhydrido clusters with pseudo-tetrahedral geometry”, Dalton Trans., 46, 5631-5643 (2017). 10.1039/C6DT04523E

R. Shimogawa, T. Takao, H. Suzuki, “Half-sandwich Cyclopentadienyl Iridium Dichloride Monomer Cp‡IrCl2 (Cp‡: 1,2,4-tri-tert-butylcyclopentadienyl)”, Chem. Lett., 46, 197-199 (2017). 10.1246/cl.160937

T. Kuzutani, Y. Torihata, H. Suzuki, T. Takao, “Synthesis of a Heterometallic Trinuclear Cluster of Ruthenium and Platinum with a Linear Alignment”, Organometallics, 35, 2543-2556 (2016). 10.1021/acs.organomet.6b00449

R. Shimogawa, T. Takao, H. Suzuki, “Modified synthesis of mixed-ligand dinuclear Ru-Ir, Ru-Rh, and Ru-Ru polyhydride-bridged complexes, CpsRuH3ML (Cps = C5Me5 (Cp*), C5tBu3H2 (Cp‡); M = Rh, Ir, Ru; L = C5(CH3)5, C6H6, p-CH3C6H4CH(CH3)2)”, J. Organomet. Chem., 818, 168-178 (2016). 10.1016/j.jorganchem.2016.06.011

M. Nagaoka, T. Kawashima, H. Suzuki, T. Takao, “Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by a Trinuclear Complex of Ruthenium and Cobalt”, Organometallics, 35, 2348-2360 (2016). 10.1021/acs.organomet.6b00277

R. Shimogawa, G. Konishi, T. Takao, H. Suzuki, "Photoinduced Reactions of Diruthenium Tetrahydride Complexes: Carbon–Hydrogen Bond Cleavage of Tetrahydrofuran Leading to Bridging Cyclic Fischer-Type Carbene Complexes”, Organometallics, 35(10), 1446-1457 (2016). 10.1021/acs.organomet.6b00070

T. Kaneko, E. Murotani, R. Tenjimbayashi, H. Suzuki,T. Takao, “Photolysis of triruthenium μ3-alkyne complexes capped by a μ3-oxo ligand”, J. Organomet. Chem., 812, 167-176 (2016). 10.1016/j.jorganchem.2015.10.016

R. Shimogawa, T. Takao, H. Suzuki, "Versatile and Highly Efficient Synthesis of Diruthenium Tetrahydride Complex”,J. Organomet. Chem., 801, 6-9 (2016). 10.1016/j.jorganchem.2015.10.009

M. Nagaoka, H. Tsuruda, M. Amako, H. Suzuki, T. Takao, "μ3-η2:η2:η2-Coordination of Primary Silane on a Triruthenium Plane”, Angew. Chem. Int. Ed., 54(49), 14871-14874 (2015). 10.1002/anie.201506969R1

M. Nagaoka, T. Shima, T. Takao, and H. Suzuki, "Trinuclear μ3‑Silyl Complexes of Ruthenium and Group 9 Metals Having 3c-2e Interactions and Transformation of a μ3‑Silyl Complex of Ru2Ir into μ‑Silyl and μ3‑Silylene Complexes”, Organometallics, 33(24), 7232-7240 (2014). 10.1021/om5010308

M. Oishi, M. Oshima, and H. Suzuki, "A Study on Zr–Ir Multiple Bonding Active for C–H Bond Cleavage", Inorg. Chem., 53(13), 6634-6654 (2014). 10.1021/ic500258g

M. Oishi, T. Endo, M. Oshima, and H. Suzuki, "Aluminum-Stabilized Low-Spin Iron(II) Hydrido Complexes of 1,4,7-Trimethyl-1,4,7-triazacyclononane", Inorg. Chem., 53(10), 5100-5108 (2014). 10.1021/ic500195q

R. Shimogawa, T. Takao, G. Konishi, H. Suzuki, "Photochemical Reaction of Diruthenium Tetrahydride-Bridged Complexes with Carbon Dioxide: Insertion of CO2 into a Ru–H Bond versus C═O Double-Bond Cleavage", Organometallics, 33(19), 5066-5069(2014). 10.1021/om500615u

T. Takao, H. Suzuki, “Activation of Linear Alkanes by a Hydrido Triruthenium Cluster and Associated Skeletal Rearrangements”, Bull. Chem. Soc. Jpn., 87(4), 443-458 (2014). 10.1246/bcsj.20130294

R. Shimogawa, T. Takao, H. Suzuki, "Synthesis, Characterization, and Reactions of Ru(II), Ru(III), and Ru(IV) Complexes with Sterically Demanding 1,2,4-Tri-tert-butylcyclopentadienyl Ligands”, Organometallics, 33(1), 289-301 (2014). 10.1021/om401035y

T. Yanagi, H. Suzuki, M. Oishi, “Synthesis and Properties of Diruthenium Tetrahydrides Supported by Less-substituted, Sterically Demanding Poly-tert-butylated Cyclopentadienyls”, Chem. Lett., 42, 1403-1405 (2013). 10.1246/cl.130699

T. Kaneko, T. Takao, H. Suzuki, “A Triruthenium Complex Capped by a Triply Bridging Oxoboryl Ligand”, Angew. Chem. Int. Ed., 52(45), 11884-11887 (2013). 10.1002/anie.201306531

T. Kaneko, H. Suwa, T. Takao, H. Suzuki, “Intramolecular Borylene Transfer Leading to the Formation of a μ3-BC2 Ring on a Triruthenium Plane”, Organometallics, 32(3), 737-740 (2013). 10.1021/om3012079

H. Suzuki, R. Shimogawa, Y. Muroi, T. Takao, M. Oshima, G. Konishi, “Bimetallic Activation of 2-Alkanones through Photo-Induced a-Hydrogen Abstraction Mediated by a Dinuclear Tetrahydride Complex”, Angew. Chem. Int. Ed., 52(6), 1773-1776 (2013). 10.1002/anie.201208185

A. Tahara, M. Kajigaya, T. Takao, H. Suzuki, “Complex Containing μ3-η2(||)-Ethyne and μ3-Methylidyne Ligands: Equilibrium of an Ethyne–Hydrido Complex with a Nonclassica μ3-Vinyl Complex”, Organometallics, 32(1), 260-271 (2013). 10.1021/om301064y

M. Nagaoka, T. Shima, T. Takao, H. Suzuki, “Synthesis of a Heterometallic Trinuclear Cluster of Ruthenium and Iridium Containing a Perpendicularly Coordinated Alkyne Ligand and Its Dynamic Behavior”, J. Organomet. Chem., 725, 68-75 (2013). 10.1016/j.jorganchem.2012.12.002